千葉大学 大学院理学研究科 基板理学専攻 反応有機化学研究室

Togo Laboratory

Press

学術原著論文 2018年

  1. "Preparation of Phenanthridines from o-Cyanobiaryls via Addition of Organic Lithiums to Nitriles and Imino Radical Cyclization with Iodine"
    A. Kishi, K. Moriyama, and H. Togo, J. Org. Chem. 2018, xx, xxxx-xxxx DOI: 10.1021/acs.joc.6b02303
    Graphical abstract
  2. "One-Pot Preparation of Aromatic Amides, 4-Aryltiazoles, and 4-Arylimidazoles from Arene"
    T. Yamamoto, and H. Togo Eur. J. Org. Chem. 2018, 30, 4187-4196 DOI: 10.1002/ejoc.201800730
    Graphical abstract
  3. "Facile One-Pot Preparation of 5-aryltetrazoles and 3-arylisoxazoles from aryl bromides"
    E. Kobayashi, and H. Togo Tetrahedron. 2018, 74, 4226-4235 DOI: 10.1016/j.tet.2018.06.044
    Graphical abstract
  4. "One-Pot Preparation of 3-Arylisoxazole-4,5-dicarboxylates from Benzylic Chlorides and Acetylenedicarboxylates"
    T. Imai, and H. Togo Eur. J. Org. Chem. 2018, 11, 1377-1383 DOI: 10.1002/ejoc.201701726
    Graphical abstract
  5. "One-pot preparation of 4-aryl-3-bromocoumarins from 4-aryl-2-propynoic acids with diaryliodonium salts, TBAB, and Na2S2O8"
    T. Sasaki, K. Moriyama, and H. Togo Beilstein J. Org. Chem. 2018, 14, 345-353 DOI: 10.3762/bjoc.14.22
    Graphical abstract
       

学術原著論文 2017年

  1. "Hydroxymethylation of Quiolines with Na2S2O8 via Radical Pathway"
    Luan Zhou, Naoki Okugawa, and H. Togo, Eur. J. Org. Chem. 2017, 41, 6239-6245 DOI: 10.1002/ejoc.201701321
    Graphical abstract
  2. "Preparation of 3-Iodoquinolines from N-Tosyl-2-propynylamines with Diaryliodonium Triflate and N-Iodosuccinimide"
    T. Sasaki, K. Moriyama, and H. Togo, J. Org. Chem. 2017 82(22), 11727-11734 DOI: 10.1021/acs.joc.7b01433
    Graphical abstract Synfactsに紹介されました。
    "Synthesis of Iodoquinolines from N-Tosyl-2-propynylamines"
    Synfacts 2017, 13(10),1016 DOI: 10.1055/s-0036-1591319

  3. "One-Pot Preparation of C1-Homologated Aliphatic Nitriles from Aldehydes through a Wittig Reaction under Metal-Cyanide-Free Conditions"
    M. Ezawa, and H. Togo, Eur. J. Org. Chem. 2017, 16, 2379-2384 DOI: 10.1002/ejoc.201700277
    Graphical abstract
  4. "Introduction of Quinolines and Isoquinolines onto Nonactivated α-C-H Bond of Tertiary Amides through a Radical Pathway"
    N. Okugawa, K. Moriyama, and H. Togo, J. Org. Chem. 2017, 82(1), 170-178 DOI: 10.1021/acs.joc.6b02303
    Graphical abstract

学術原著論文 2016年

  1. "Synthetic utility of iodic acid in the oxidation of benzylic alcohols to aromatic aldehydes and ketones"
    S.Imai, and H. Togo, Tetrahedron, 2016, 72, 6948-6954 DOI: 10.1016/j.tet.2016.09.019
    Graphical abstract
  2. "Preparation of 5-Aryl-2-Alkyltetrazoles with Aromatic Aldehydes, Alkylhydrazine, Di-tert-butyl Azodicarboxylate, and [Bis(trifluoroacetoxy)iodo]benzene"
    T.Imai, R.Harigae, K.Moriyama, and H. Togo, J. Org. Chem. 2016, 81(9), 3975-3980 DOI: 10.1021/acs.joc.6b00606
    Graphical abstract Synfactsに紹介されました。
    "Regioselective Preparation of Tetrazoles without the Use of Azides"
    Synfacts 2016, 12(7), 671 DOI: 10.1055/s-0035-1562358

  3. "Direct Preparation of 3-Iodochromenes from 3-Aryl- and 3-Alkyl-2-propyn-1-ols with Diaryliodonium Salts and NIS"
    T. Sasaki, K. Miyagi, K. Moriyama, and H. Togo, Org. Lett. 2016, 18, 944-947 DOI: 10.1021/acs.orglett.5b03651
    Graphical abstract
  4. "Direct Transformation of Ethylarenes into Primary Aromatic Amides with N-Bromosuccinimide and I2-Aqueous NH3"
    S. Shimokawa, Y. Kawagoe, K. Moriyama, and H. Togo, Org. Lett. 2016, 18, 784-787 DOI: 10.1021/acs.orglett.6b00048
    Graphical abstract

学術原著論文 2015年

  1. "One-Pot Transformation of Aliphatic Carboxylic Acids into N-Alkylsuccin-imides with NIS and NCS/NaI"
    Y. Nakai, K. Moriyama, and H. Togo, Eur. J. Org. Chem. 2016, 4, 768-772 DOI: 10.1002/ejoc.201501315
    Graphical abstract
  2. "Transformation of N,N-Diisopropylarylmethylamines into N-Isopropylaryl-methylamines with Molecular Iodine"
    M. Ezawa, K. Moriyama, and H. Togo, Tetrahedron Lett. 2015, 56, 6689-6692 DOI: 10.1016/j.tetlet.2015.10.044
    Graphical abstract
  3. "Oxidative Oxygen-Nucleophilic Bromo-Cyclization of Alkenyl Carbonyl Compounds Without Organic Wastes Using Alkali Metal Reagents in Green Solvent"
    K. Moriyama, C. Nishinohara, T. Sugiue, and H. Togo, RSC Adv. 2015, 5, 85872-85878 DOI: 10.1039/C5RA19851H
    Graphical abstract
  4. "Divergent Synthesis of α,γ-Disubstituted γ-Butyrolactones through Diastereoselective Bromolactonization with Alkali Metal Bromide: Asymmetric Total Synthesis of (+)-Dubiusamine C"
    K. Moriyama, T. Sugiue, C. Nishinohara, and H. Togo, J. Org. Chem. 2015, 80(18), 9132-9140 DOI: 10.1021/acs.joc.5b01497
    Graphical abstract
  5. "Introduction of Ether Groups onto Electron-Deficient Nitrogen-Containing Heteroaromatics Using Radical Chemistry under Transition-Metal-Free Conditions"
    N. Okugawa, K. Moriyama, and H. Togo, Eur. J. Org. Chem. 2015, 22, 4973-4981 DOI: 10.1002/ejoc.201500584
    Graphical abstract
  6. "One-pot preparation of 2,5-disubstituted and 2,4,5-trisubstituted oxazoles from aromatic ketones with molecular iodine, oxone, and trifluoromethanesulfonic acid in nitriles"
    S. Imai, H. Kikui, K. Moriyama, and H. Togo, Tetrahedron, 71(13), 5267-5274 DOI: 10.1016/j.tet.2015.06.022
    Graphical abstract
  7. "2,6-Bis(amido)benzoic Acid with Internal Hydrogen Bond as Bronsted Acid Catalyst for Friedel-Crafts Reaction of Indoles"
    K. Moriyama, T.Sugiue, Y.Saito, S.Katsuta, and H. Togo, Adv. Synth. Cat. 357(9),2143-2149 DOI: 10.1002/adsc.201401189
    Graphical abstract
  8. "A One-Pot, Transition-Metal-Free Procedure for C-O, C-S, and C-N Bond Formation at the Benzylic Position of Methylarenes"
    H. Shimojo, K. Moriyama, and H. Togo, Synthesis 2015, 47(09),1280-1290 DOI: 10.1055/s-0034-1380069
    Graphical abstract
  9. "Facile One-Pot Transformation of Arenes into Aromatic Nitriles under Metal-Cyanide-Free Conditions"
    T. Tamura, K. Moriyama, and H. Togo, Eur. J. Org. Chem. 2015, 2023-2029 DOI: 10.1002/ejoc.201403672
    Graphical abstract

学術原著論文 2014年

  1. "Regioselective Csp2-H Dual Functionalization of Indoles Using Hypervalent Iodine(III): Bromo-Amination via 1,3-Migration of Imides on Indolyl(phenyl)iodonium Imides"
    K. Moriyama, K. Ishida, and H. Togo, Chem. Commun. 2014, 51, 2273-2276 DOI: 10.1039/C4CC09077B
    Graphical abstract
  2. "One-Pot Preparation of 2-Arylbenzofurans from Oximes with Diaryliodonium Triflate"
    K.Miyagi, K. Moriyama, and H. Togo, Heterocycles 2014, 89(9), 2122-2136 DOI: 3987/COM-14-13071
    Graphical abstract
  3. "Facile One-Pot Transformation of Phenols into o-Cyanophenols"
    Y.Nakai, K. Moriyama, and H. Togo, Eur. J. Org. Chem. 2014, 6077-6083 DOI: 10.1002/ejoc.201402817
    Graphical abstract
  4. "Oxidative Debenzylation of N-Benzyl Amides and O-Benzyl Ethers Using Alkali Metal Bromide"
    K. Moriyama, Y. Nakamura, and H. Togo, Org. Lett. 2014, 16(14), 3812-3815 DOI: 10.1021/ol501703y
    Graphical abstract
  5. "One-Pot Transformation of Methylarenes into Aromatic Nitriles with Inorganic Metal-Free Reagents"
    Y. Kawagoe, K. Moriyama, and H. Togo, Eur. J. Org. Chem. 2014, 4115-4122 DOI: 10.1002/ejoc.201402270
    Graphical abstract
  6. "The Selective Oxidation of Alcohols Using Alkali Metal Bromides as Bromide Catalysts: A Experimental Study of the Reaction Mechanism"
    K. Moriyama, M. Takemura, and H. Togo, J. Org. Chem. 2014, 79(13), 6094-6104 DOI: 10.1021/jo5008064
    Graphical abstract
  7. "One-Pot Transformation of Methylarenes into Aromatic Aldehydes under Metal-Free Conditions"
    M. Tabata, K. Moriyama, and H. Togo, Eur. J. Org. Chem. 2014, 3402-3410 DOI: 10.1002/ejoc.201402015
    Graphical abstract
  8. "Preparation of 3,5-Disubstituted Pyrazoles and Isoxazoles from Terminal Alkynes, Aldehydes, Hydrazines, and Hydroxylamine"
    R.Harigae, K. Moriyama, and H. Togo, J. Org. Chem. 2014, 79(5), 2049-2058 (2014) DOI: 10.1021/jo4027116
    Graphical abstract
  9. "Oxidation of Alcohols to Aldehydes or Ketones with 1-Acetoxy-1,2-benziodoxole-3(1H)-one Derivatives"
    M.Iinuma, K. Moriyama, and H. Togo, Eur. J. Org. Chem. 2014, 772-780 DOI: 10.1002/ejoc.201301466
    Graphical abstract

学術原著論文 2013年

  1. "Transition-Metal-Free Transformation of Aryl Bromides into Aromatic Esters and Amides via Aryl Trichloromethyl Ketones"
    S. Dohi, K. Moriyama, and H. Togo, Eur. J. Org. Chem. 2013, 7815-7822 DOI: 10.1002/ejoc.201301170
    Graphical abstract
  2. "One-Pot Transformation of Carboxylic Acids into Nitriles"
    K. Miyagi, K. Moriyama, and H. Togo, Eur. J. Org. Chem. 2013, 5886-5892 DOI: 10.1002/ejoc.201300629
    Graphical abstract
  3. "Direct Oxidative Conversion of Methylarenes into Aromatic Nitriles"
    D. Tsuchiya, Y. Kawagoe, K. Moriyama, and H. Togo, Org. lett. 15(16), 4194-4197 (2013). DOI: 10.1021/ol401906q
    Graphical abstract
  4. "Facile Oxidation of Alcohols to Aldehydes or Ketones with 1-Acetoxy-5-nitro- 1,2-benziodoxole-3(1H)-one"
    M. Iinuma, K. Moriyama, and H. Togo, Synlett 24(13), 1707-1711 (2013). DOI: 10.1055/s-0033-1339283
    Graphical abstract
  5. "Simple One-Pot Conversion of Alcohols into Nitriles"
    H. Shimojo, K. Moriyama, and H. Togo, Synthesis 45(15), 2155-2164 (2013). DOI: 10.1055/s-0033-1338489
    Graphical abstract
  6. "Facile preparation of amides from carboxylic acids and amines with ion-supported Ph3P"
    Y. Kawagoe, K. Moriyama, and H. Togo, Tetrahedron 69, 3971-3977 (2013). DOI: 10.1016/j.tet.2013.03.021
    Graphical abstract
  7. "Various oxidative reactions with novel ion-supported (diacetoxyiodo)benzenes"
    M. Iinuma, K. Moriyama, and H. Togo, Tetrahedron 69, 2961-2970 (2013). DOI: 10.1016/j.tet.2013.02.017
    Graphical abstract
  8. "Iodine-Mediated α-Sulfonyloxylation of Alkyl Aryl Ketones with Oxone® and Sulfonic Acids"
    K. Kikui, K. Moriyama, and H. Togo, Synthesis 45, 791-797 (2013).DOI: 10.1055/s-0032-1318199
    Graphical abstract

学術原著論文 2012年

  1. "Practical One-pot Conversion of Aryl Bromides and β-Bromostyrenes into Aromatic Nitriles and Cinnamonitriles"
    G. Ishii, R. Harigae, K. Moriyama and H. Togo, Tetrahedron 69, 1462-1469 (2013) DOI: 10.1016/j.tet.2012.12.022
    Graphical abstract
  2. "Facile Preparation of Unsymmetrical Diaryl Ethers from Unsymmetrical Diaryliodonium Tosylates and Phenols with High Regioselectivity"
    Y. Kakinuma, K. Moriyama and H. Togo, Synthesis 45, 183-188 (2013) DOI: 10.1055/s-0032-1316824
    Graphical abstract
  3. "Brønsted Acid-assisted Intramolecular Aminohydroxylation of N-Alkenylsulfonamides under Heavy Metal-free Conditions"
    K. Moriyama, Y. Izumisawa and H. Togo, J. Org. Chem. 77, 9846-9851 (2012).DOI: 10.1021/jo301523a
    Graphical abstract
  4. "Simple and Practical Method for Preparation of [(Diacetoxy)iodo]arenes with Iodoarenes and
    m-Chloroperoxybenzoic Acid"
    M. Iinuma, K. Moriyama and H. Togo, Synlett 23, 2663-2666 (2012).DOI: 10.1055/s-0032-1317345
    Graphical abstract
  5. "Effect of catalytic alkali metal bromide on Hofmann-type rearrangement of imides"
    K. Moriyama, K. Ishida and H. Togo, Chem. Commun. 48, 8574-8576 (2012).DOI: 10.1039/C2CC33914E
    Graphical abstract
  6. "Efficient Swern oxidation and Corey-Kim oxidation with ion-supported methyl sulfoxides and methyl sulfides"
    D. Tsuchiya, M. Tabata, K. Moriyama and H. Togo, Tetrahedron 68, 6849-6855 (2012).DOI: 10.1016/j.tet.2012.06.026
    Graphical abstract
    開発した試薬が東京化成工業(株)から販売されます!
    イオン固定型メチルスルフィド
    1-Methyl-3-[6-(methylthio)hexyl]imidazolium p-Toluenesulfonate
    製品コード:M2321
    東京化成工業(株)のページへ
    tci
  7. "Practical one-pot preparation of ketones from aryl and alkyl bromides with aldehydes and DIH via Grignard Reagents"
    S. Dohi, K. Moriyama and H. Togo, Tetrahedron 68, 6557-6564(2012).DOI: 10.1016/j.tet.2012.05.059
    Graphical abstract
  8. "TEMPO-Mediated Oxidation of Alcohols with Ion-Supported (Diacetoxyiodo)benzenes"
    Y. Suzuki, M. Iinuma, K. Moriyama and H. Togo, Synlett 23, 1250-1256(2012).DOI: 10.1055/s-0031-1290766
    Graphical abstract
  9. "Facile preparation of aromatic esters from aromatic bromides with ethyl formate or DMF and molecular iodine via aryllithium"
    S. Ushijima, K. Moriyama and H. Togo, Tetrahedron 68, 4701-4709 (2012).DOI: 10.1016/j.tet.2012.04.016

  10. "Practical one-pot transformation of electron-rich aromatics into aromatic nitriles with molecular iodine and aq NH3 using Vilsmeier?Haack reaction"
    S. Ushijima, K. Moriyama and H. Togo, Tetrahedron 68, 4588-4595 (2012).DOI: 10.1016/j.tet.2012.04.034

  11. “Direct and Selective Benzylic Oxidation of Alkylarenes via C-H Abstraction Using Alkali Metal Bromides”
    K. Moriyama, M. Takemura and H. Togo, Org. Lett. 14, 2414-2417 (2012).DOI: 10.1021/ol300853z
    Graphical abstract
  12. “Preparation of N,N-Dimethyl Aromatic Amides from Aromatic Aldehydes with Dimethylamine and Iodine Reagents”
    H.Baba, K. Moriyama and H. Togo, Synlett 23, 1175-1180 (2012).DOI: 10.1055/s-0031-1290659
    Graphical abstract
  13. “Aza-Morita-Baylis-Hillman Reaction with Ion-supported Ph3P”
    Y. Imura, N Shimojuh, K. Moriyama and H. Togo, Tetrahedron, 68, 2319-2325 (2012).DOI: 10.1016/j.tet.2012.01.034
    Graphical abstract
    Volume 68, Issue 10 の表紙になりました!
    cover
    cover
  14. “Hofmann-Type Rearrangement of Imides by in Situ Generation of Imide-Hypervalent Iodines(III) from Iodoarenes”
    K. Moriyama, K. Ishida, and H. Togo, Org. Lett., 14, 946-949 (2012).DOI: 10.1021/ol300028j
    Graphical abstract
  15. “Facile Preparation of Aromatic Ketones from Aromatic Bromides and Arenes with Aldehydes”
    S. Ushijima, S. Dohi, K. Moriyama, and H. Togo, Tetrahedron, 68, 1436-1442 (2012).DOI: 10.1016/j.tet.2011.12.023
    Graphical abstract

書籍

  1. 東郷秀雄、“化学便覧”内「ハロゲン化合物」
    丸善 (2012年12月).
  2. 東郷秀雄、“ヨードベンゼンを触媒とした金属フリーの複素環合成”、「触媒の設計・反応制御 事例集」第4章4節
    技術情報協会 (2012年12月).
  3. 東郷秀雄、“最新の有機化学演習”、全278ページ
    裳華房 (2012年12月).

マスコミ掲載

  1. 日経産業新聞 3月28日
    「医療・液晶向け中間体芳香族ニトリル: ヨウ素原料、1工程で合成」
  2. 日経産業新聞 5月10日 先端人 千葉大学 東郷秀雄
    「非主流にこだわり研究」 化学合成の工程大幅削減」
  3. 読売新聞 10月11日夕刊 千葉大学 東郷秀雄
    「ヨウ素・液晶パネル明減を制御」

学術原著論文 2011年

  1. “Swern Oxidation of Alcohols with Ion-Supported Methyl Sulfoxide and Oxalyl Chloride”
    D. Tsuchiya, K. Moriyama, and H. Togo, Synlett, 2701-2704 (2011).DOI: 10.1055/s-0031-1289552
    Graphical abstract
  2. “Preparation of α-Bromoketones and Thiazoles from Ketones with NBS and Thioamides in Ionic Liquids”
    Y.Izumisawa, and H. Togo, Green & Sustainable Chem., 1, 54-62 (2011).DOI: 10.4236/gsc.2011.13010

  3. “Facile Transformation of Esters to Nitriles”
    Y. Suzuki, K. Moriyama, and H. Togo, Tetrahedron, 67, 7956-7962. (2011).DOI: 10.1016/j.tet.2011.08.028
    Graphical abstract
  4. “Oxidative Intramolecular Bromo-Amination of N-Alkenyl Sulfonamides via Umpolung of Alkali Metal Bromides”
    K. Moriyama, Y. Izumisawa, and H. Togo, J. Org. Chem., 76, 7249-7255. (2011).DOI: 10.1021/jo201113r
    Graphical abstract
  5. “Iodoarene-Mediated α-Tosyloxylation of Ketones with mCPBA and p-Toluenesulfonic Acid”
    A. Tanaka, K. Moriyama, and H. Togo, Synlett, 1853-1858. (2011). DOI: 10.1055/s-0030-1260948
    Graphical abstract
  6. “Benzylic-acetoxylation of alkylbenzenes with PhI(OAc)2 in the presence of catalytic amounts of TsNH2 and I2”
    H. Baba, K. Moriyama, and H. Togo, Tetrahedron Lett., 52, 4303-4307. (2011). DOI: 10.1016/j.tetlet.2011.06.036
    Graphical abstract
  7. “Direct Transformation of N,N-Disubstituted Amides and Isopropyl Esters to Nitriles”
    Y. Suzuki, T. Yoshino, K. Moriyama, and H. Togo, Tetrahedron, 67, 3809-3814 (2011). DOI: 10.1016/j.tet.2011.04.008
    Graphical abstract
  8. “Transformation of Aromatic Bromides into Aromatic Nitriles via Formations of Grignard Reagents and Their DMF Adducts”
    G. Ishii, K. Moriyama, and H. Togo, Tetrahedron Lett., 52, 2404~2406 (2011). DOI: 10.1016/j.tetlet.2011.02.110
    Graphical abstract
  9. “One-pot conversion of aromatic bromides and aromatics into aromatic nitriles via aryllithiums and their DMF adduct”
    S. Ushijima, K. Moriyama, and H. Togo, Tetrahedron, 67, 958~964 (2011). DOI: 10.1016/j.tet.2010.11.109
    Graphical abstract
  10. “Wittig reaction with ion-supported Ph3P”
    N. Shimojuh, Y. Imura, K. Moriyama, and H. Togo, Tetrahedron, 67, 951~957 (2011). DOI: 10.1016/j.tet.2010.11.111
    Graphical abstract

書籍

  1. 東郷秀雄、“改訂 有機人名反応”、全387ページ
    講談社サイエンティフィック (2011年11月).
  2. 森山克彦、「ヨウ素を用いる複素環化合物合成」“ヨウ素の化学と最新応用技術 (Up-to-date Chemistry & Technological Application for Iodine)”、p114-124
    シーエムシー出版 (2011年).

学術原著論文 2010年

  1. “Desulfonyloxyiodination of Arenesulfonic Acids with mCPBA and Molecular Iodine”,
    Y. Suzuki, Y. Ishiwata, K. Moriyama, and H. Togo, Tetrahedron Lett., 51, 5950~5953 (2010). DOI: 10.1016/j.tetlet.2010.09.034
  2. “Metal-Free One-pot Oxidative Conversion of Benzylic Alcohols and Benzylic Halides into Aromatic Amides with Molecular Iodine in aq. Ammonia, and Hydrogen Peroxide”,
    R. Ohmura, M. Takahata, and H. Togo, Tetrahedron Lett., 51, 4378~4381 (2010). DOI: 10.1016/j.tetlet.2010.06.051
  3. “An Efficient Preparation of Chroman Derivatives from 3-Aryl-1-propanols and Related Compounds with 1,3-Diiodo-5,5-dimethylhydantoin under Irradiation Conditions”,
    S. Furuyama and H. Togo, Synlett, 2325~2329 (2010). DOI: 10.1055/s-0030-1258017
  4. “Direct Oxidative Conversiton of Aldehydes into 2-Substituted 1,4,5,6-Tetrahydropyrimidines Using Molecular Iodine or 1,3-Diiodo-5,5-dimethylhydantoin”,
    S. Takahashi and H. Togo, Heterocycles, 82, 593-601 (2010) . DOI: 10.3987/COM-10-S(E)29
  5. “One-pot Conversion of Aromatic Bromides and Aromatics into Aromatic Nitriles”,
    S. Ushijima, and H. Togo, Synlett, 1562~1566 (2010). DOI: 10.1055/s-0029-1219935
  6. “Novel Preparation of Polymer-Supported Iodobenzene and Its Synthetic Utility as a Recyclable Reagent with m-Chloroperbenzoic Acid”,
    Y. Suzuki and H. Togo, Synthesis, 2355~2360 (2010). DOI: 10.1055/s-0029-1218795
  7. “Sulfonylamidation of Alkylbenzenes at Benzylic Position with p-Toluenesulfonamides and 1,3-Diiodo-5,5-dimethylhydantoin”,
    H.Baba and H. Togo, Tetrahedron Lett., 51, 2063~2066 (2010). DOI: 10.1016/j.tetlet.2010.02.060
  8. “Novel Preparation of Ion-supported Triphenylphosphines and Their Synthetic Utility”,
    Y. Imura, N.Shimojuh, Y. Kawano and H. Togo, Tetrahedron, 66, 3421~3426 (2010). DOI: 10.1016/j.tet.2010.03.039
  9. “Iodoarene-Mediated Cyclization of N-Methoxy-2-arylethanesulfonamides with Oxone”,
    Y. Ishiwata, Y. Suzuki, and H. Togo, Heterocycles, 339-348 (2010). DOI: 10.3987/COM-10-S(E)4
  10. “Metal-free One-pot Conversion of Electron-rich Aromatics into Aromatic Nitriles”,
    S. Ushijima and H. Togo, Synlett, 1067~1070 (2010). DOI: 10.1055/s-0029-1219575

書籍

  1. 東郷秀雄、“ 有機反応のしくみと考え方”、新訂版、全387ページ
    講談社サイエンティフィック (2010年).
  2. 東郷秀雄、第8章 “ 単体ヨウ素を用いた簡便な有機合成”、p. 279~p. 291、『日本初ブロックバスターを目指して-創薬研究最前線』
    シーエムシー出版 (2010年).

学術原著論文 2009年

  1. “Facile Preparation of 3,4-Dihydro-2,1-benzothiazine 2,2-dioxide and Related Reactions with 1,3-Diiodo-5,5-dimethylhydantoin under Photochemical Conditions”,
    S. Furuyama and H. Togo, Synlett, 1336~1340 (2009).
  2. “An Efficient Conversion of Aldehydes into 2-Substituted 2-Oxazolines Using 1,3-Diiodo-5,5-dimethylhydantoin”,
    S. Takahashi and H. Togo, Synlett, 2329~2332 (2009).
  3. “Direct Oxidative Conversion of Alkyl Halides into Nitriles with Molecular Iodine and 1,3-Diiodo-5,5-dimethylhydantoin in Ammonia”,
    S. Iida, R. Ohmura, and H. Togo, Tetrahedron, 65, 6257~6262 (2009).
  4. “Iodoarene-Catalyzed One-pot Preparation of 2,4,5-Trisubstituted Oxazoles from Alkyl Aryl Ketones with mCPBA in Nitriles”,
    Y. Kawano and H. Togo, Tetrahedron, 65, 6251~6256 (2009) .
  5. “3-Exo-tet Cyclization of 2,2-Disubstituted 1,3-Dihalopropanes with Indium in Aqueous and Ionic Liquid Solvent System”,
    Y. Tsuchiya, Y. Izumisawa, and H. Togo, Tetrahedron, 65, 7533~7537 (2009).
  6. “Facile Preparation of Thiazoles from 1H-(1'-Alkynyl)-5-methyl-1,2,3-benz-iodoxathiole 3,3-Dioxide with Thioamides”,
    Y. Ishiwata and H. Togo, Synlett, 2637~2641 (2009).
  7. “Iodoarene-Mediated One-pot Preparation of 2,5-Disubstituted and 2,4,5-Trisubstituted Oxazoles from Alkyl Aryl Ketones with Oxone in Nitriles”,
    Y. Ishiwata and H. Togo, Tetrahedron, 65, 10720~10724 (2009).
  8. “4-MeC6H4-Mediated Efficient α-Tosyloxylation of Ketones with Oxone and p-Toluenesulfonic Acid in Acetonitrile”,
    A. Tanaka and H. Togo, Synlett, 3360~3364 (2009).

書籍

  1. 東郷秀雄、“ 基礎有機化学 身近な有機化合物を中心に”、全250ページ
    東京化学同人、印刷中(2009年).
  2. 東郷秀雄、“ 有機反応のしくみと考え方”、新訂版、全400ページ、講談社サイエンティフィック、印刷中(2010年).

学術原著論文 2008年

  1. “Iodoarene-mediated One-pot Preparation of 2,4,5-Trisubstituted Oxazoles from Ketones”
    Y. Kawano and H. Togo, Synlett, 217~220 (2008).
  2. “Efficient Preparation of 2-Imidazolines from Aldehydes and Ethylenediamine with 1,3-Diiodo-5,5-dimethylhydantoin”,
    S. Takahashi and H. Togo, Heterocycles, 76, 507~514 (2008).
  3. “Iodobenzene-Catalyzed Preparation of 3,4-Dihydro-1H-2,1-benzothiazine 2,2- Dioxide from 2-Aryl-N-methoxyethanesulfonamides with m-Chloroperoxy-benzoic Acid”,
    A. Moroda and H. Togo, Synthesis, 1257~1261 (2008).
  4. “Radical 3-exo-tet Cyclization of 1,3-Dihalopropanes with SmI2 to form Cyclopropanes”,
    T, Ohkita, Y. Tsuchiya, and H. Togo, Tetrahedron, 64, 7247~7251 (2008) .
  5. “Direct Oxidative Conversion of Alkyl Halides into Nitriles with Molecular Iodine in aq. Ammonia”,
    S. Iida and H. Togo, Synlett, 1639~1642 (2008).
  6. “Facile Preparation of Thiazoles from 1H-(1'-Alkynyl)-5-methyl-1,2,3-benz-iodoxathiole 3,3-Dioxide with Thioamides”,
    Y. Ishiwata and H. Togo, Synlett, 2637~2641 (2008).
  7. “単体ヨウ素を用いた有機合成反応”,
    有機合成化学協会誌 66巻、7月号、652~663 (2008).

書籍

  1. 東郷秀雄、“ 基礎有機化学 身近な有機化合物を中心に”、全250ページ、
    東京化学同人、(2008年1月).

学術原著論文 2007年

  1. “Macroporous Polystyrene-Supported (Diacetoxyiodo)benzene: An Efficient Heterogeneous Oxidizing Reagent” ,
    Y. Shang, T. Y. S. But, H. Togo, P. H. Toy, Synlett, 67~70 (2007)
  2. “Direct Oxidative Conversion of Aldehydes and Alcohols to 2-Imidazolines and 2-Oxazolines Using Molecular Iodine”,
    M. Ishihara and H. Togo, Tetrahedron, 63, 1474~1480 (2007).
  3. “Oxidative Conversion of Primary Alcohols, and Primary, Secondary, and Tertiary Amines to the Corresponding Nitriles with 1,3-Diiodo-5,5-dimethylhydantoin in aq. NH3.”,
    S. Iida and H. Togo, Synlett, 407~410 (2007).
  4. “PhI- and Polymer-supported PhI-Catalyzed Oxidative Conversion of Ketones and Alcohols to a-Tosyloxyketones with m-Chloroperbenzoic Acid and p-Toluene- sulfonic Acid”,
    Yukiharu Yamamoto, Yuhta Kawano, Patrick H. Toy, and Hideo Togo*, Tetrahedron, 63, 4680~4687 (2007).
  5. “Facile Preparation of 2-Imidazolines from Aldehydes with t-Butyl Hypochlorite”,
    Midori Ishihara and Hideo Togo, Synthesis, 1939~1942 (2007).
  6. “Direct Oxidative Conversion of Alcohols and Amines to Nirtriles with Molecular Iodine and DIH in aq. NH3”,
    S. Iida and H. Togo, Tetrahedron, 63, 8274~8281 (2007) .
  7. “Efficient Conversion of Ketones to α-Tosyloxyketones with m-Chloroperbenzoic Acids and p-Toluenesulfonic Acid in the Presence of Catalytic Amount of IL-Supported PhI im[emim]OTs”,
    J. Akiike, Y. Yamamoto, H. Togo, Synlett, 2168~2172 (2007).
  8. “意外と身近なヨウ素”, 
    日本化学会誌「化学と教育」55巻、11号、566~569 (2007).
  9. 東郷秀雄、“ 演習有機反応 その解き方と考え方”、全251ページ、
    講談社サイエンティフィク(2007年7月刊行)

学術原著論文 2006年

  1. ”Efficient Esterification of Carboxylic acids and Phosphonic Acids with Trialkyl Orthoacetate in Ionic Liquid"
    T. Yoshino, S. Imori, and H. Togo,Tetrahedron, 62, 1309~1317 (2006).
  2. “An Efficient Preparation of 2-Imidazolines and Imidazoles from Aldehydes with Molecular Iodine and (Diacetoxyiodo)benzene”
    M. Ishihara and H. Togo,Synlett, 227~230 (2006).
  3. ”PhI-Catalyzed a-Tosyloxylation of Ketones with m-Chloroperbenzoic Acid and p-Toluenesulfonic Acid"
    Y. Yamamoto and H. Togo, Synlett, 798~800 (2006).
  4. ”Direct and Facile Oxidative Conversion of Primary, Secondary, and Tertiary Amines to the Corresponding Nitriles"
    S. Iida and H. Togo, Synlett, 2633~2635 (2006).
  5. ”Efficient Demethylation of N,N-Dimethylanilines with Phenyl Chloroformate in Ionic Liquids"
    S. Imori and H. Togo, Synlett, 2629~2632 (2006).
  6. ”Synthetic Use of Molecular Iodine for Organic Synthesis"
    H. Togo and S. Iida, Synlett, 2159~2175 (2006).
  7. ”Biphenyl- and Terphenyl-Based Recyclable Organic Trivalent Iodine Reagents"
    A. Moroda and H. Togo, Tetrahedron, 62, 12408~12414 (2006).

学術原著論文 2005年

  1. ”Facile Preparation of Polymer-Supported Methyl Sulfonate and Its Recyclable Use for Methylation of Carboxylic Acids and Amines"
    T. Yoshino and H. Togo,Synlett,517~519 (2005).
  2. “A Multipolymer System for Organocatalytic Alcohol Oxidation”
    T. Y. S. But, Y. Tashino, H. Togo, and P. H. Toy, Org. & Biomol. Chem.,3, 970~971 (2005).
  3. ”I2-Mediated Photochemical Preparation of 2-Substituted 1,3-Dioxolanes and Tetrahydrofurans from Alcohols with Polymer-Supported Hypervalent Iodine Reagents, PSDIB"
    T. Teduka and H. Togo, Synlett,923~926 (2005).
  4. ”Facile Oxidative Conversion of Alcohols to Esters Using Molecular Iodine"
    N. Mori and H. Togo, Tetrahedron, 61, 5915~5925 (2005).
  5. ”Facile Oxidative Conversion of Alcohols to Nitriles Using Molecular Iodine in Ammonia Water"
    N. Mori and H. Togo, Synlett, 1456~1458 (2005).
  6. ”Preparation and Synthetic Use of Polymer-Supported Acetoacetate Reagent"
    T. Hirai and H. Togo, Synthesis,2664~2668 (2005).
  7. ”Facile Preparation of Cyclopropanes from 2-Iodoethyl-substituted Olefines and 1,3-Dihalopropane with Zinc Powder"
    D. Sakuma and H. Togo, Tetrahedron, 61, 10138~10145 (2005).
  8. ”Facile One-pot Preparation of [Hydroxy(sulfonyloxy)iodo]arenes from iodoarenes with mCPBA in the Presence of Sulfonic Acids"
    Y. Yamamoto and H. Togo, Synlett, 2486~2488 (2005).
  9. “有機人名反応 そのしくみとポイント”
    東郷秀雄、306ページ
    講談社サイエンティフィク, Willy (2005年7月).
  10. “ヨウ素化合物の機能と応用”における第4章“ヨウ素の化学反応”
    東郷秀雄
    シーエムシー出版 (2005年).

学術原著論文 2004年

  1. ”Facile Conversion of Alcohols to the Corresponding 2,2,2-Trifluoroethyl Esters with Molecular Iodine and Potassium Carbonate in 2,2,2-Trifluoroethanol”,
    N. Mori and H. Togo, Synlett, 880~882 (2004)
  2. “Environmentally Friendly Esterification of Carboxylic Acids with Triethyl Orthoacetate in Ionic Liquid”,
    T. Yoshino and H. Togo, Synlett, 1604~1606 (2004)
  3. ”TEMPO-Mediated Environmentally Benign Oxidation of Primary Alcohols to Carboxylic Acids with Poly[4-(diacetoxyiodo)styrene]”,
    Y. Tashino and H. Togo, Synlett, 2010~2012 (2004).
  4. “Environmentally Benign Preparation of Heteroaromatics from Ketones or Alcohols, with Macroporous Polystyrenesulfonic Acid and (Diacetoxyiodo)benzene, Followed by Thioamide, Amidine, and 2-Aminopyridine”,
    M. Ueno and H. Togo, Synthesis, 2673~2677 (2004).
  5. “Facile and Environmentally Benign Zn-Mediated Cyclopropanation of Electron-Deficient 2-Iodoethyl-Substituted Olefins via Radical 3-exo-trig Manner”,
    D. Sakuma and H. Togo, Synlett, 2501~2504 (2004).
  6. “Advanced Free Radical Reactions for Organic Synthesis”,268 pages,
    Hideo Togo,Elsevier Science (2004年1月刊行).

学術原著論文 2003年

  1. 実験化学講座 第5版,19巻 “有機化合物の合成” 2章
    東郷秀雄  “ラジカル反応” 丸善 (2003).
  2. “環境に優しいラジカル反応試剤TPDSを用いた有機反応”
    東郷秀雄、 ファインケミカル、 5月号、 44~53 (2003)
  3. Preparation of 3,4-Dihydro-2,1-benzothiazine 2,2-dioxide with Polymer-supported Hypervalent Iodine Reagents,
    K.Sakuratani,H.Togo,ARKIVOC,11~20 (2003).
  4. Novel Preparation of 2,1-benzothiazine Derivatives from Sulfonamides with [Hydroxy(tosyloxy)iodo]arenes,
    Y.Misu,H.Togo,Org. Biomol. Chem.,1, 1342~1346 (2003).
  5. Environmentally Friendly TEMPO-mediated Oxidation of Alcohols with Poly[4-(diacetoxyiodo)styrene],
    K.Sakuratani and H.Togo,Synthesis, 21~23 (2003).
  6. Environmentally Friendly Wohl-Ziegler Bromination : Ionic-liquid Reaction and Solvent-Free Reaction,
    H.Togo,T.Hirai,Synlett,702~704 (2003).
  7. Novel Oxidative α-Tosyloxylation of Alcohols with Iodosylbenzene and p-Toluenesulfonic Acid,and Its Synthetic Application for the Direct Preparation of Heteroaromatics,
    M. Ueno,T.Nabana,and H.Togo,J. Org. Chem.,68,6424~6425 (2003).
  8. Zinc- and Indium-mediated Ring-Expansion Reaction of α-Halomethyl Cyclic β-Keto Esters in Aqueous Alcohol,
    M.Sugi,D.Sakuma,and H.Togo,J. Org. Chem.,68,7629~7633 (2003).
  9. “1,1,2,2-Tetraphenyldisilane”
    Encyclopedia of Reagents for Organic synthesis,
    Hideo Togo,ed.by L.A.Paquatte, Willy (2003).
  10. “2,2'-Dipyridyl Disulfide-N,N'-dioxide”
    Encyclopedia of Reagents for Organic synthesis
    Hideo Togo,ed.by L.A.Paquatte, Willy (2003).

学術原著論文 2002年

  1. Environmentally Friendly TPDS-Mediated Free Radical Ring Expansion of α-Haloalkyl Cyclic β-Keto Esters,
    Masaaki Sugi and H.Togo,Tetrahedron,58,3171~3175 (2002).
  2. Polymer-Supported Hypervalent Iodine Reagents,
    H.Togo and K.Sakuratani,Synlett,1966-1975 (2002).
  3. Reactivity of Novel [Hydroxy(tosyloxy)iodo]arenes and [Hydroxy(phosphoryloxy)iodo]arenes for α-Tosyloxylation and α-Phosphoryloxylation of Ketones,
    T.Nabana and H.Togo,J. Org. Chem. 67,4362~4365 (2002).
  4. “環境調和型化学変換試剤 : 高分子リサイクル型超原子価ヨウ素酸化剤の開発と展開”
    東郷秀雄、エコインダストリー(Eco Industry)、7巻、6月号、5~18 (2002).
  5. “高性能ポリマー型酸化試剤”
    東郷秀雄、櫻谷憲司、化学と工業 (日本化学会誌) 55巻、9月号、1018~1020 (2002).
  6. 東郷秀雄、“有機反応のしくみと考え方”
    講談社サイエンティフィク、273ページ、(2002年).

学術原著論文 2001年

  1. Novel Preparation and Reactivity of Poly[4-hydroxy(tosyloxy)iodo]styrenes,
    S. Abe, K. Sakuratani, and H. Togo, Synlett, 22~24 (2001).
  2. Synthetic Use of 1,1,2,2-Tetraphenyldisilane for the Preparation of Biaryls Through the Intramolecular Free Radical ipso-Substitution of N-(2-Bromoaryl)-arenesulfonamides,
    A. Ryokawa and H. Togo, Synlett, 57、5915~5921 (2001).
  3. Synthetic Use of Poly[4-hydroxy(tosyloxy)iodo]styrenes,
    S. Abe, K. Sakuratani, and H. Togo, J. Org. Chem., 66、6174~6177 (2001).
  4. Oxidatively Sonochemical Dealkylation of Various N-Alkylsulfonamides to Free Sulfonamides and Aldehydes,
    Masashi Katohgi and Hideo Togo, Tetrahedron,57, 7481~7486 (2001).
  5. Synthetic Uses of Organohypervalent Iodine Compounds Through Radical Pathways,
    Hideo Togo and Masashi Katohgi, Synlett, 565~581 (2001).
  6. 1,1,2,2-Tetraphenyldisilane (TPDS) as a New Diversified Radical Reagent,
    H. Togo, M. Sugi, and K. Toyama,Comptes Rendus de L’Academie des Sciences Serie IIc, 539~546 (2001).
  7. 東郷秀雄、“有機フリーラジカルの化学”
    講談社サイエンティフィク、187ページ, (2001年).

学術原著論文 2000年

  1. Preparation of 3,4-Dihydro-2,1-benzothiazine 2,2-Dioxide Skeleton from N-Methyl 2-(Aryl)ethane sulfonamides with (Diacetoxyiodo)arenes,
    H.Togo, Y.Harada, and M.Yokoyama, J. Org. Chem., 65, 926~929 (2000).
  2. Deoxygenative Functionalization of Hydroxy Groups via Xanthates with Tetraphenyldisilane,
    H.Togo, S. Matsubayashi, O. Yamazaki, and M. Yokoyama, J. Org. Chem., 65, 2816~2819 (2000).
  3. Iodophosphoryloxylation of Carbon-Carbon Multi-Bonds and Its Application to Glycals,
    T. Muraki, M. Yokoyama, and H. Togo, J. Org. Chem., 65, 4679~4684 (2000).
  4. Radical Cyclization of O-Glycosides Using 1,1,2,2-Tetraphenyldisilane as a Radical Reagent: Preparation of Bicyclic Sugars,
    O. Yamazaki, K. Yamaguchi, M. Yokoyama, and H. Togo, J. Org. Chem., 65, 5440~5442 (2000).
  5. Novel Sonochemical Dealkylation of N-Alkylsulfonamides in the Presence of (Diacetoxyiodo)benzene and Iodine,
    M. Katohgi, M. Yokoyama, and H. Togo, Synlett, 1055~1057 (2000).
  6. Preparation and Reactivities of Novel (Diacetoxyiodo)arenes Bearing Heteroaromatics,
    H. Togo, T. Nabana, and K. Yamaguchi, J. Org. Chem., 65, 8391~8394 (2000).